Western University Academic Calendar. - 2020ARCHIVE
Chemistry 4483A/B
ELUCIDATION OF ORGANIC AND BIOORGANIC MECHANISMS
Techniques for diagnosing and testing mechanisms of chemical reactions, with an emphasis on organic and bioorganic examples: kinetics, activation parameters, Bronsted catalysis law, Hammett and Taft relations, Marcus Theory, kinetic isotope effects, solvent effects. An introduction to pericyclic reactions with a discussion of aromaticity and orbital symmetry.